C11：色氨酸（Trp；tryptophan）

称谓

色氨酸 tryptophan Trp

3D结构

C1=CC=C2C(=C1)C(=CN2)C[C@@H](C(=O)O)N

$结构式：$

-

\usepackage{chemfig} % 加载chemfig宏包
\begin{document}
\chemfig{
CH	(-[,1]COOH)
	(-[2,1]NH_2
		-[2,0.5,,,transparent] % 上边缘支撑
	)
	(-[4,1]CH_2
        -[4,1]
        *5(
            =-[,,,2]HN-[,,2,]*6(
				-=
                -=
                -
            )=-
        )
	)
}
\end{document}

-

\usepackage{chemfig} % 加载chemfig宏包
\begin{document}
\chemfig{
C	(-[2,1]COOH
		-[2,0.5,,,transparent] % 上边缘支撑
	)
	(<[7.3,1]NH_2)
	(<:[,1]H)
	(-[4.7,1]CH_2
        -[4,1]
        *5(
            =-[,,,2]HN-[,,2,]*6(
				-=
                -=
                -
            )=-
        )
	)
}
\end{document}

^2

-

\usepackage{chemfig} % 加载chemfig宏包
\begin{document}
\chemfig{
    % 氨基酸核心骨架（与你提供的结构完全兼容，保留氨基、羧基、α-H）
    C
    (-[4,1]H_3N^{+})
    (-[2,1]COO^{-})
    (-[0,1]H)
    (-[6,1]CH_2
        -[6,1]
        *5(
            =-N(-[6,0.3]H)-*6(
				-=
                -=
                -
            )=-
        )
    )
}
\end{document}

^1

-

\usepackage{chemfig} % 加载chemfig宏包
\begin{document}
\chemfig{
    % 氨基酸核心骨架（与你提供的结构完全兼容，保留氨基、羧基、α-H）
    C
    (-[4,1]H_3N^{+})
    (-[2,1]COO^{-})
    (-[0,1]H)
    (-[6,1]CH_2
        -[6,1]
        *5(
            -*6(
				-=
                -=
                -
            )=-[,,,1]NH-[,,1]=
        )
    )
}
\end{document}

^1-2

---

-

\usepackage{chemfig} % 加载chemfig宏包
\begin{document}
\chemfig{
    % 氨基酸核心骨架（与你提供的结构完全兼容，保留氨基、羧基、α-H）
    C
    (<[4,1]H_2N)
    (<:[2,1]COOH
		-[2,0.5,,,transparent] % 上边缘支撑
    )
    (<[0,1]H)
    (<:[6,1]CH_2
        -[6,1]
        *5(
            =-N(-[6,0.3]H)-*6(
				-=
                -=
                -
            )=-
        )
    )
}
\end{document}

^3

-

\usepackage{chemfig}
\begin{document}
\chemfig{
	(-[0.7,1]COOH)
	(<[6,1]NH_2
		-[2,0.5,,,transparent] % 上边缘支撑
	)
	(-[3.3,1]-[4.7,1]
		-[3.3,1]
		*5(
			=-N(-[2,0.3,,,,transparent]H
				-[2,0.5,,,transparent] % 上边缘支撑
			)-*6(
				-=
				-=
				-
			)=-
		)
	)
}
\end{document}

^4

-

\usepackage{chemfig}
\begin{document}
\chemfig{
	(-[0.7,1]COOH)
	(<[6,1]NH_2)
	(-[3.3,1]-[4.7,1]
		-[3.3,1]
		*5(
			=-N(-[2,0.3,,,,transparent]H
				-[2,0.5,,,transparent] % 上边缘支撑
			)-*6(
				-=
				-=
				-
			)=-
		)
	)
}
\end{document}

• 形成肽链

\usepackage{chemfig}
\begin{document}

%% 色氨酸a
\definesubmol\trpa{
N
	(-[::60,0.3,,,transparent]H)
	-[::-60]
		(<:[::-60]-[::30]
	        *5(
	            -*6(
					-=
	                -=
	                -
	            )=-[,,,1]NH-[,,1]=
	        )
		)
	-[::60]
		(=[::60]O)
}
%% 色氨酸b
\definesubmol\trpb{
N
	(-[::-60,0.3,,,transparent]H)
	-[::60]
		(<[::60]-[::30]
	        *5(
	            -*6(
					-=
	                -=
	                -
	            )=-[,,,2]HN-[,,2]=
	        )
		)
	-[::-60]
		(=[::-60]O)
}
\chemfig{
H
	-[::+30]!\trpa
	-[::-60]!\trpb
	-[::+60]!\trpa
	-[::-60]!\trpb
	-[::+60]!OH
}
\end{document}

^5-1

• 形成肽链-带颜色

\usepackage{chemfig}
\begin{document}

%% 色氨酸a
\definesubmol\trpa{
N
	(-[::+60,0.3,,,,transparent]H)
	-[::-60]
		(<:[::-60,,,,green]-[::30,,,,blue]
			*5([::0,,,,blue]
	            -*6(
					-=
	                -=
	                -
	            )=-[,,,1]\textcolor{blue}{N}(-[0,0.26,,,,transparent]\textcolor{blue}{H})-[,,1]=
	        )
		)
	-[::60]
		(=[::60]O)
}
%% 色氨酸b
\definesubmol\trpb{
N
	(-[::-60,0.3,,,transparent]H)
	-[::60]
		(<[::60,,,,green]-[::30,,,,blue]
			*5([::0,,,,blue]
	            -*6(
					-=
	                -=
	                -
	            )=-[,,,1]\textcolor{blue}{N}(-[4,0.26,,,,transparent]\textcolor{blue}{H})-[,,1]=
	        )
		)
	-[::-60]
		(=[::-60]O)
}
\chemfig{
H
	-[::+30]!\trpa
	-[::-60]!\trpb
	-[::+60]!\trpa
	-[::-60]!\trpb
	-[::+60]!OH
}
\end{document}

^5-2