称谓
6-磷酸葡萄糖酸内酯酶 6-phosphogluconolactonase PGLS
催化反应
> Tip: 没有酶催化，也能发生
[[C6：6-磷酸-葡萄糖酸内脂（6-Phosphogluconolactone）]]+$ <->[[C6：6-磷酸-葡萄糖酸（6-Phosphogluconic acid）]]+^+$
$化学方程式：$
-
\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00} % P
\begin{document}
\chemname{
\chemfig[cram width=2pt]{
%[:-30]
%C4
(-[2,0.5]H)(-[6,0.5,,2]HO)
*6(
%C3
<(-[6,0.5]H)(-[2,0.5]OH)
%C2
-[,1,,, line width=2pt](-[2,0.5]H)(-[6,0.5]OH)
%C1
>(=[0,0.5]O)
-O-
%C5
(-[2,0.5,,]CH_2O
% P
(-[0,0.35,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
% 上边界支撑
-[2,0.5,,,,transparent])
)-
)
}
}{6-phosphogluconolactone}
\quad\quad
+$
\quad\quad
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {6-phosphogluconolactonase} (4.6,0);
\end{tikzpicture}
\quad\quad
\chemname{
\chemfig[atom sep=2em]{
%纵向对齐
-[2,3,,,,transparent]
C(=[1]O)(-[3]^{-}O)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]HO)(-H)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]H)(-OH)
-[6]CH_2OP
% P
(-[0,0.54,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
% 下边界支撑
-[6,0.5,,,,transparent])
}
}{6-phosphogluconic acid}
\quad\quad
+
^+$
\end{document}^1
• P366
\usepackage{chemfig}
\begin{document}
\chemname{
\chemfig[cram width=2pt]{
[2]*6(
%2
(-[6,0.5]OH)(-[2,0.5]H)
%1
>(=[0,0.5]O)
%O
-O
%5
-(-[2]CH_2OPO_3^{2-})
%4
-(-[6,0.5,,2]HO)(-[2,0.5]H)
%3
<(-[2,0.5,,]OH)(-[6,0.5]H)
-[,,,,line width=2pt](-[6,0.5]OH)
)
}
}{6-phosphogluconolactone}
\quad\quad
+$
\quad\quad
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {6-phosphogluconolactonase} (4.6,0);
\end{tikzpicture}
\quad\quad
\chemname{
\chemfig[atom sep=2em]{
%纵向对齐
-[2,4,,,,transparent]
C(=[1]O)(-[3]^{-}O)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]HO)(-H)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]H)(-OH)
-[6]CH_2OP_3^{2-}
}
}{6-phosphogluconic acid}
\quad\quad
+
^+$
\end{document}-
\usepackage{chemfig}
\begin{document}
\chemfig{
(=[,0.8]O)
(-[5,0.5]
(<:[7,0.8]OH)
(-[4,0.5]
(<[5,0.8]HO)
(-[3,0.5]
(<:[4,0.8]HO)
(-[1,0.5]
(<[2,0.8]
-[3.5,0.8]\fbox{P}
)
(-[,0.5]O
(-[7,0.5])
)
)
)
)
)
}
+$
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {PGLS} (1,0);
\end{tikzpicture}
\chemfig{
COOH
(-[6,0.5]C(-[,0.8]OH)
(-[6,0.5]C(-[4,0.8]HO)
(-[6,0.5]C(-[,0.8]OH)
(-[6,0.5]C(-[,0.8]OH)
(-[6,0.5]C-[,0.8]\fbox{P})
)
)
)
)
}
+^+$
\end{document}-
\usepackage{chemfig}
\begin{document}
\chemfig{
(=[,0.8]O)
(-[5,0.5]
(<:[7,0.8]OH)
(-[4,0.5]
(<[5,0.8]HO)
(-[3,0.5]
(<:[4,0.8]HO)
(-[1,0.5]
(<[2,0.8]
-[3.5,0.8]\fbox{P}
)
(-[,0.5]O
(-[7,0.5])
)
)
)
)
)
}
+$
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {PGLS} (1,0);
\end{tikzpicture}
\chemfig{
(-[3.5,0.8]HO)
(=[6,0.8]O)
(-[0.5,0.5]
(<:[2,0.8]OH)
(-[7.5,0.5]
(<:[6,0.8]OH)
(-[0.5,0.5]
(<:[2,0.8]OH)
(-[7.5,0.5]
(<[6,0.8]OH)
(-[0.5,0.5]-[7.5,0.8]\fbox{P})
)
)
)
)
}
+^+$
\end{document}