HMP：非氧化阶段

描述

![[HMP：非氧化阶段.png]]

flowchart TB
a[5-磷酸-核酮糖]
b[5-磷酸-核糖]
c[5-磷酸-木酮糖]
d{"转酮酶：催化1"}
e[7-景天庚酮糖]
f[3-磷酸-甘油醛]
g{"转醛酶"}
h[果糖-6-磷酸]
i[赤癣糖-4-磷酸]
j{"转酮酶：催化2"}
a<--"磷酸戊糖异构酶"-->b
b<-->d
f<-->g
e<-->g
g<-->i
g<-->h
i<-->j
h<-->j
j<-->h
j<-->c
c<-->d
d<-->f
d<-->e
c<--"磷酸戊糖表异构酶"-->a

• [[1.1. 磷酸戊糖异构酶（5PRI）]]

• [[1.2. 磷酸戊糖表异构酶（RPE）]]

• [[2. 转酮酶：催化1]]

• [[4. 转酮酶：催化2]]

• [[3. 转醛酶（TAL）]]

[[HMP：接其他反应]]

合并

6 [[C5：核酮糖-5-磷酸（ribulose 5-phosphate，Ru5P，RuMP）]]+$->5 [[C6：葡糖-6-磷酸（glucose 6-phosphate，G6P）]] + Pi

$化学方程式：$ -

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
\begin{document}

\chemfig{6}
\chemname{
\chemfig[atom sep=2em]{
%纵向对齐
-[2,2,,,,transparent]
CH_2OH
-[6]C(=O)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]H)(-OH)
-[6]CH_2O
	% P
	(-[0,0.54,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
	% 下边界支撑
	-[6,0.5,,,,transparent])
}
}{ribulose 5-phosphate}
+$

\begin{tikzpicture} 
\draw [->] (0,0) to node[above] {} (1,0); 
\end{tikzpicture}
5
\chemname{
\chemfig[cram width=2pt]{
	%[:-30]
	%C4
	(-[2,0.5]H)(-[6,0.5,,2]HO)
	*6(
	%C3
	<(-[6,0.5]H)(-[2,0.5]OH)
	%C2
	-[,1,,, line width=2pt](-[2,0.5]H)(-[6,0.5]OH)
	%C1
	>(-[2,0.5]H)(-[6,0.5]OH)
	-O-
	%C5
	(-[2,0.5,,]CH_2O
				% P
				(-[0,0.35,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
				% 上边界支撑
				-[2,0.5,,,,transparent])
	)-
	)
}
}{glucose 6-phosphate}

+Pi

\end{document}

^1

-

\usepackage{chemfig}
\begin{document}

\chemfig{6}
\chemfig{
	(-[6,0.5]OH)
	(-[0.5,0.5]
		(=[2,0.5]O)
		(-[7.5,0.5]
			(<[6,0.8]OH)
			(-[0.5,0.5]
				(<:[2,0.8]OH)
				(-[7.5,0.5]
					(-[0.5,0.8]\fbox{P})
				)
			)
		)
	)
}
+$

\begin{tikzpicture} 
\draw [->] (0,0) to node[above] {} (1,0); 
\end{tikzpicture}
5
\chemfig{
	(-[,0.5]OH)
	(<[5,0.5]
		(-[7,0.5]OH)
		(-[4,0.5,,, line width=2pt]
			(-[5,0.5]HO)
			(>[3,0.5]
				(-[4,0.5]HO)
				(-[1,0.5]
					(-[2,0.5]
						(-[3.5,0.8]\fbox{P})
					)
					(-[,0.5]O
						(-[7,0.5])
					)
				)
			)
		)
	)
} 

+Pi

\end{document}