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C6：果糖-6-磷酸（F6P）

fructose 6-phosphate smiles C C@H C@H C@@H C =O CO O O O OP =O O O fructose 6-phosphate F6P 9次绘制 $结构式：$ - tikz \usepackage chemfig \definecolor cpk P rgb 1.00, 0.50, 0.00

作者：admin

称谓

fructose 6-phosphate

3D结构

C([C@H]([C@H]([C@@H](C(=O)CO)O)O)O)OP(=O)(O)O

果糖-6-磷酸

fructose 6-phosphate F6P

分子结构

9次绘制

$结构式：$ -

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
\begin{document}

\chemname{
\chemfig[cram width=2pt]{
	%5-6
		(-[6,0.5]H)
		(-[0.7,1.25]O)
			%6
			(-[2,1.25,,]CH_2O
				% P
				(-[0,0.35,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
				% 上边界支撑
				-[2,0.5,,,,transparent])
			)
	%4
	<[6.75,](-[6,0.35]-[6,0.15,,,transparent]-[0,0.13,,,transparent]{\color{pink}OH})(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.35,,]-[2,0.15,,,transparent]-[4,0.13,,,transparent]{\color{blue}HO})(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.35]-[2,0.15,,,transparent]-[0,0.13,,,transparent]{\color{green}OH})(-[3.3,1.05])
	%1
	-[6,0.5]CH_2{\color{red}OH}
}
}{}
\end{document}

-

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
\begin{document}

\chemfig[atom sep=2em]{
CH_2OH
-[6]C(=O)
-[6]C(-[4]HO)(-H)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]H)(-OH)
-[6]CH_2O
	% P
	(-[0,0.54,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
	% 下边界支撑
	-[6,0.5,,,,transparent])
}

\end{document}

• P369

\usepackage{chemfig}
\begin{document}

\chemfig[atom sep=2em]{
CH_2OH
-[6]C(=O)
-[6]C(-[4]HO)(-H)
-[6]C(-[4]H)(-OH)
-[6]C(-[4]H)(-OH)
-[6]CH_2OP_3^{2-}
}

\end{document}

-

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
%\definecolor{cpk_P}{rgb}{0.8, 0.4, 0.0}       % P
%\definecolor{cpk_P_custom}{rgb}{1.00, 0.498, 0.165}       % P
%\definecolor{cpk_P}{named}{Orchid}     % P
\definecolor{cpk_H}{rgb}{1.00, 1.00, 1.00}    % 氢 - 白色
\definecolor{cpk_C}{rgb}{0.50, 0.50, 0.50}    % 碳 - 灰色（CPK 标准）
\definecolor{cpk_C_black}{rgb}{0.00, 0.00, 0.00} % 碳 - 黑色（备选）
\definecolor{cpk_N}{rgb}{0.00, 0.20, 0.80}    % 氮 - 深蓝色（CPK 标准）
\definecolor{cpk_O}{rgb}{0.80, 0.00, 0.00}    % 氧 - 鲜红色（CPK 标准）
\definecolor{cpk_S}{rgb}{1.00, 1.00, 0.00}    % 硫 - 亮黄色（CPK 标准）
\begin{document}
%\setchemfig{bond offset=0pt,node style={draw,minimum size=0pt}}
\setchemfig{cram width=2pt}
%\setchemfig{bond offset=0pt,node style={draw=none,circle,fill=cyan,minimum size=0pt}}
\chemfig[cram width=2pt]{
	%5-6
		(-[6,0.5]H)
		(-[0.7,1.25]O)(-[2,,,]CH_2
			-[2,0.8]O
			% 键重绘
			(-[2,0.8,,,,cpk_P])
			% P
			(-[2,1,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(10pt);}P}
			% 上边界支撑
			-[2,0.5,,,,transparent])
		)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
}
\end{document}

-

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
\begin{document}
%\setchemfig{bond offset=0pt,node style={draw,minimum size=0pt}}
\chemfig[cram width=2pt]{
	%5-6
		(-[6,0.5]H)
		(-[0.7,1.25]O)
			%6
			(-[2,1.25,,]CH_2O
				% P
				(-[0,0.35,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(6pt);}P}
				% 上边界支撑
				-[2,0.5,,,,transparent])
			)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
}
\end{document}

^1

-

\usepackage{chemfig}
\definecolor{cpk_P}{rgb}{1.00, 0.50, 0.00}     % P
%\definecolor{cpk_P}{rgb}{0.8, 0.4, 0.0}       % P
%\definecolor{cpk_P_custom}{rgb}{1.00, 0.498, 0.165}       % P
%\definecolor{cpk_P}{named}{Orchid}     % P
\definecolor{cpk_H}{rgb}{1.00, 1.00, 1.00}    % 氢 - 白色
\definecolor{cpk_C}{rgb}{0.50, 0.50, 0.50}    % 碳 - 灰色（CPK 标准）
\definecolor{cpk_C_black}{rgb}{0.00, 0.00, 0.00} % 碳 - 黑色（备选）
\definecolor{cpk_N}{rgb}{0.00, 0.20, 0.80}    % 氮 - 深蓝色（CPK 标准）
\definecolor{cpk_O}{rgb}{0.80, 0.00, 0.00}    % 氧 - 鲜红色（CPK 标准）
\definecolor{cpk_S}{rgb}{1.00, 1.00, 0.00}    % 硫 - 亮黄色（CPK 标准）
\begin{document}
%\setchemfig{bond offset=0pt,node style={draw,minimum size=0pt}}
\setchemfig{cram width=2pt}
%\setchemfig{bond offset=0pt,node style={draw=none,circle,fill=cyan,minimum size=0pt}}
\chemfig[cram width=2pt]{
	%5-6
		(-[6,0.5]H)
		(-[0.7,1.25]O)
			%6
			(-[2,1.25,,]CH_2O
				% P
				(-[0,0.5,,,,transparent]{\chemmove{\draw[ultra thick,green,fill=cpk_P,line width=2pt] (0.1,0.12)circle(10pt);}P}
				% 上边界支撑
				-[2,0.5,,,,transparent])
			)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
}
\end{document}

• P328

\usepackage{chemfig}
\begin{document}
\chemfig[cram width=2pt]{
	%5-6
	(-[6,0.5]H)(-[0.7,1.25]O)(-[2,,,5]{\chemmove{\draw[color=green,fill=red,line width=5pt,thick] (0.17,0.2)circle(6pt);}^{2-}}O_3POCH_2
	%支撑
	(-[2,0.5,,,transparent])
	)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
}
\end{document}

• P328

\usepackage{chemfig}
\begin{document}
\chemfig[cram width=2pt]{
	%5-6
	(-[6,0.5]H)(-[0.7,1.25]O)(-[2,,,5]^{2-}O_3POCH_2)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
}
\end{document}

• P328

\usepackage{chemfig}
\begin{document}
\chemfig[cram width=2pt]{
%6
^{2-}O_3POCH_2
	%5
	-[6,,4](-[6,0.5]H)(-[0.7,1.25]O)
	%4
	<[6.75,](-[6,0.5]OH)(-[2,0.5]H)
	%3
	-[,,,, line width=2pt](-[2,0.5,,2]HO)(-[6,0.5]H)
	%2
    >[1.25,](-[2,0.5]OH)(-[3.3,1.05])
	%1
	-[6,0.5]CH_2OH
} 
\end{document}

-

\usepackage{chemfig}
\begin{document}
\chemfig{
	(-[2,0.5]OH)
	(>[5,0.5]
		(-[3,0.6])
		(<:[7.5,0.8]OH)
		(-[5,0.5]
			(<[7,0.8]OH)
			(-[4,0.5]
				(<:[5,0.8]HO)
				(-[3,0.5]
					(-[1,0.85]O)
					(<[3,0.5]
						(-[2,0.8]\fbox{P})
					)
				)
			)
		)
	)
}

\end{document}

产生

[[0. 磷酸己糖异构酶（PHI）--葡萄糖-6-磷酸异构化]] [[3. 转醛酶（TAL）]] [[4. 转酮酶：催化2]]

参与反应

[[0. 磷酸己糖异构酶（PHI）--葡萄糖-6-磷酸异构化]] [[0. 磷酸果糖激酶-1（PFK-1）--果糖-6-磷酸磷酸化]] [[3. 转醛酶（TAL）]] [[4. 转酮酶：催化2]]