称谓
顺乌头酸酶 顺式乌头酸酶 aconitase
催化反应
[[C6：柠檬酸（Citric Acid）]]<-->$+[[C6：顺乌头酸（cis-aconitate）]]
$化学方程式：$
-
\usepackage{chemfig}
\begin{document}
\chemfig{
C
(-[,0.5]COO^{-})
(-[2,0.5]CH_2-[,0.5]COO^{-})
(-[4,0.5]HO)
(-[6,0.5]CH_2-[,0.5]COO^{-})
}
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {aconitase} (1,0); % 水平箭头
\end{tikzpicture}
\chemfig{
C
(-[,0.5]COO^{-})
(-[2,0.5]CH_2-[,0.5]COO^{-})
(=[6,0.5]CH-[,0.5]COO^{-})
}
+
\chemfig{H_2O}
\end{document}-
\usepackage{chemfig}
\begin{document}
\chemfig{
C
(-[,0.5]COOH)
(-[2,0.5]CH_2-[,0.5]COOH)
(-[4,0.5]HO)
(-[6,0.5]CH_2-[,0.5]COOH)
}
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {aconitase} (1,0); % 水平箭头
\end{tikzpicture}
\chemfig{
C
(-[,0.5]COOH)
(-[2,0.5]CH_2-[,0.5]COOH)
(=[6,0.5]CH-[,0.5]COOH)
}
+
\chemfig{H_2O}
\end{document}-
\usepackage{chemfig}
\begin{document}
\chemfig{
C
(-[6,0.5]
(=[7.5,0.5]O)(-[4.5,0.5]HO))
(-[2,0.5]OH)
(-[4,0.5]
(-[3,0.5]
(=[1.5,0.5]O)(-[4,0.5]HO)
)
)
(-[,0.5]
(-[1,0.5]
(=[2.5,0.5]O)(-[,0.5]OH)
)
)
}
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {aconitase} (1,0); % 水平箭头
\end{tikzpicture}
\chemfig{
(-[4.5,0.8]
(-[3.5,0.8]
(-[2,0.5]OH)
(=[4.5,0.5]O)
)
)
(=[7.5,0.8]
(-[0.5,0.8]
(=[2,0.5]O)
(-[7.5,0.5]OH)
)
)
(-[2,0.8]
(-[0.5,0.5]OH)
(=[3.5,0.5]O)
)
}
+
\chemfig{H_2O}
\end{document}-
OC(=O)CC(O)(C(=O)O)CC(=O)O>>O=C(O)CC(=CC(=O)O)C(=O)O.O[[C6：顺乌头酸（cis-aconitate）]]+$<-->[[C6：异柠檬酸（isocitric）]]
$化学方程式：$
-
\usepackage{chemfig}
\begin{document}
\chemfig{
C
(-[,0.5]COO^{-})
(-[2,0.5]CH_2-[,0.5]COO^{-})
(=[6,0.5]CH-[,0.5]COO^{-})
}
+\chemfig{H_2O}
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {aconitase} (1,0); % 水平箭头
\end{tikzpicture}
\chemfig{
CH
(-[,0.5]COO^{-})
(-[2,0.5]CH_2-[,0.5]COO^{-})
(-[6,0.5]CH
(-[,0.5]COO^{-})
(-[4,0.5]HO)
)
}
\end{document}-
\usepackage{chemfig}
\begin{document}
\chemfig{
(-[4.5,0.8]
(-[3.5,0.8]
(-[2,0.5]OH)
(=[4.5,0.5]O)
)
)
(=[7.5,0.8]
(-[0.5,0.8]
(=[2,0.5]O)
(-[7.5,0.5]OH)
)
)
(-[2,0.8]
(-[0.5,0.5]OH)
(=[3.5,0.5]O)
)
}
+\chemfig{H_2O}
\begin{tikzpicture}
\draw [<->] (0,0) to node[above] {aconitase} (1,0); % 水平箭头
\end{tikzpicture}
\chemfig{
(<[4,0.5]
(=[3,0.5]O)
(-[4.5,0.5]HO)
)
(-[1.5,0.5]
(-[3,0.5]
(=[4,0.5]O)
(-[1.5,0.5]OH)
)
)
(-[7,0.5]
(<[,0.8]OH)
(-[5,0.5]
(=[4,0.5]O)
(-[7,0.5]OH)
)
)
}
\end{document}-
O=C(O)CC(=CC(=O)O)C(=O)O.O>>O=C(O)C(CC(=O)O)C(O)C(=O)O下一步
[[3. TAC：异柠檬酸氧化脱羧：异柠檬酸脱氢酶（IDH）]]